Thursday, February 24, 2011

Aromaticity

Organic molecules exist in many different forms. They are generally classified into two major groups called aliphatic organic molecules and aromatic organic molecules. Aliphatic compounds are those that contain C – C single bonds and/or double bonds. Aromatic compounds also contain these bonds but they are special that they are planar, cyclic molecules with all the C atoms having conjugated double bonds, meaning that the electron clouds of all the C atoms overlap those of the adjacent C atoms’. An electron cloud is a group of negatively charged electrons revolving around the atomic nucleus. These aromatic compounds obey Huckel’s Rule, stating that the compound must have 4n + 2π electrons in order to be classified as an aromatic compound.

The reaction of aromatic compounds is such that it is much more complex than aliphatic compounds. Because of their conjugated system, they require different kinds of chemicals, temperature regulations and much more care to assist the reactants to proceed to products. Some of the reactions involving aromatic compounds are highly useful as they can be used in synthesis of many useful drugs and other compounds.

Wednesday, February 9, 2011

after thoughts on organic 2.1 exam...

So, the first organic exam of the semester =( not happy about it. It turned out to be more time consuming and tougher than I thought it would be. But I wish I had studied a little more and looked at much more problems than I had.
The most confusing problem in the exam was Question 11 of Section 2 where we had to match the given organic compounds to the appropriate 13C NMR spectra. I had to go back multiple times and change my answers. To fully comprehend the question, I went back and read the section on 13C NMR in the textbook and one of the practice websites Dr. M suggested us.

This is a tutorial website where you get to practice 13C that I found a bit useful.
http://www.wfu.edu/~ylwong/nmr/c13/

I think that to master this whole spectroscopy business you need to just keep practicing practicing practicing and practicing.

 

Wednesday, February 2, 2011

Thursday, January 27, 2011

Infrared Spectroscopy

So I was having difficulty understanding IR spectroscopy and what Dr. M talked about on NMR and IR stuff in lab today. I couldn't understand what the graphs were supposed to mean and how we were supposed to interpret it. Upon a little extra reading from various different cites on IR spectroscopy, I pretty much get it now =)

IR Spectroscopy is used for identifying the types of functional groups present in a compound using the visible spectrum. The concept of this technique is that molecules that absorb light and specific frequencies have certain structural characteristics. These absorbed frequencies directly correspond to the type of bonding and the bond strength present between these molecules of the compound. How these frequencies are determined and how eventually the compound is identified is based on the type of vibrational mode a bond displays. In common organic compounds, these vibrational modes can be categorized into 6 vibrational modes which are symmetrical stretching, asymmetrical stretching, wagging, twisting, rocking and scissoring. Depending on the type of bonding present between the elements and also on the element itself plays an important role on the frequency, the wavelength, the absorption and how the data on that certain compound is displayed on a graph.

My sources:
http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/Spectrpy/InfraRed/infrared.htm
http://en.wikipedia.org/wiki/Infrared_spectroscopy

One down, millions to go.... =|

Wednesday, January 26, 2011